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Intramolecular Hydroamination of Unbiased and Functionalized Primary Aminoalkenes Catalyzed by a Rhodium Aminophosphine Complex

We report a rhodium catalyst that exhibits high reactivity for the hydroamination of primary aminoalkenes that are unbiased toward cyclization and that possess functional groups that would not be tolerated in hydroaminations catalyzed by more electrophilic systems. This catalyst contains an unusual...

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Detalhes bibliográficos
Main Authors: Julian, Lisa D., Hartwig, John F.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2948069/
https://ncbi.nlm.nih.gov/pubmed/20839807
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1052126
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