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Mechanism of the Enantioselective Oxidation of Racemic Secondary Alcohols Catalyzed by Chiral Mn(III)–Salen Complexes

The experiments described here clarify the mechanism and origin of the enantioselectivity of the oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)–salen complexes using HOBr, Br(2)/H(2)O/KOAc or PhI(OAc)(2)/H(2)O/KBr as a stoichiometric oxidant. Key points of the proposed pathway i...

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Sonraí Bibleagrafaíochta
Main Authors: Brown, M. Kevin, Blewett, Megan M., Colombe, James R., Corey, E. J.
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2010
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC2945693/
https://ncbi.nlm.nih.gov/pubmed/20666410
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja103103d
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