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Chiral Brønsted Acid Catalyzed Enantioselective Synthesis of anti-Homopropargyl Alcohols via Kinetic Resolution-Aldehyde Allenylboration Using Racemic Allenylboronates
[Image: see text] A chiral phosphoric acid catalyzed kinetic resolution/allenylboration of racemic allenylboronates with aldehydes is described. Allenylboration of aldehydes with 2.8 equivalents of allenylboronate (±)-1 in the presence of 10 mol% of catalyst (R)-2 provided anti-homopropargyl alcohol...
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| Главные авторы: | , , |
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| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2013
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3640598/ https://ncbi.nlm.nih.gov/pubmed/23484801 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol4003459 |
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