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Formation, Structure, and EPR Detection of a High Spin Fe(IV)–Oxo Species Derived from Either an Fe(III)–Oxo or Fe(III)–OH Complex
High spin oxoiron(IV) complexes have been proposed to be a key intermediate in numerous non-heme metalloenzymes. The successful detection of similar complexes has been reported for only two synthetic systems. A new synthetic high spin oxoiron(IV) complex is now reported that can be prepared from a w...
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| Autori principali: | , , , , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2010
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2942906/ https://ncbi.nlm.nih.gov/pubmed/20704272 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1047818 |
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