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Platinum(II)-Catalyzed Intermolecular Hydroamination of Monosubstituted Allenes with Secondary Alkylamines
A 1:1 mixture of (dppf)PtCl(2) and AgOTf (5 mol %) catalyzed the intermolecular hydroamination of monosubstituted allenes with secondary alkylamines at 80 °C to form allylic amines in good yield with selective formation of the E-diastereomer.
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2010
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2924659/ https://ncbi.nlm.nih.gov/pubmed/20177625 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b925859k |
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