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Asymmetric Catalytic N-Phosphonyl Imine Chemistry: the Use of Primary Free Amino Acids and Et(2)AlCN for Asymmetric Catalytic Strecker Reaction
The new asymmetric catalytic Strecker reaction of achiral N-phosphonyl imines has been established. Excellent enantioselectivity (95.2–99.7%ee) and yields (89–97%) have been achieved by using primary free natural amino acids as catalysts and Et(2)AlCN as nucleophile. This work also presents the nove...
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| Hauptverfasser: | , , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2010
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2912979/ https://ncbi.nlm.nih.gov/pubmed/20597482 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo100865q |
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