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Directly Relating Reduction Energies of Gaseous Eu(H(2)O)(n)(3+), n = 55–140, to Aqueous Solution: The Absolute SHE Potential and Real Proton Solvation Energy
In solution, half-cell potentials are measured relative to other half-cells resulting in a ladder of thermodynamic values that is anchored to the standard hydrogen electrode (SHE), which is assigned an arbitrary value of exactly 0 V. A new method for measuring the absolute SHE potential is introduce...
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| Main Authors: | , , , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2009
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2909332/ https://ncbi.nlm.nih.gov/pubmed/19711981 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja902815v |
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