Directly Relating Reduction Energies of Gaseous Eu(H(2)O)(n)(3+), n = 55–140, to Aqueous Solution: The Absolute SHE Potential and Real Proton Solvation Energy

In solution, half-cell potentials are measured relative to other half-cells resulting in a ladder of thermodynamic values that is anchored to the standard hydrogen electrode (SHE), which is assigned an arbitrary value of exactly 0 V. A new method for measuring the absolute SHE potential is introduce...

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Autores principales: Donald, William A., Leib, Ryan D., Demireva, Maria, O’Brien, Jeremy T., Prell, James S., Williams, Evan R.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2009
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Article
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC2909332/
https://ncbi.nlm.nih.gov/pubmed/19711981
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja902815v
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