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Directly Relating Gas-Phase Cluster Measurements to Solution-Phase Hydrolysis, the Absolute Standard Hydrogen Electrode Potential, and the Absolute Proton Solvation Energy

Solution-phase, half-cell potentials are measured relative to other half-cell potentials, resulting in a thermochemical ladder that is anchored to the standard hydrogen electrode (SHE), which is assigned an arbitrary value of 0 V. A new method for measuring the absolute SHE potential is demonstrated...

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Bibliografske podrobnosti
Main Authors: Donald, William A., Leib, Ryan D., O’Brien, Jeremy T., Williams, Evan R.
Format: Artigo
Jezik:Inglês
Izdano: 2009
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC2757329/
https://ncbi.nlm.nih.gov/pubmed/19440999
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.200900334
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