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Effects of Gas-Phase Basicity on the Proton Transfer between Organic Bases and Trifluoroacetic Acid in the Gas Phase: Energetics of Charge Solvation and Salt Bridges

The unimolecular dissociation pathways and kinetics of a series of protonated trimer ions consisting of two organic bases and trifluoroacetic acid were investigated using blackbody infrared radiative dissociation. Five bases with gas-phase basicities (GB) ranging from 238.4 to 246.2 kcal/mol were us...

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Bibliografiske detaljer
Main Authors: Strittmatter, Eric F., Wong, Richard L., Williams*, Evan R.
Format: Artigo
Sprog:Inglês
Udgivet: 2000
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC1409764/
https://ncbi.nlm.nih.gov/pubmed/16554909
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp0012505
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