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α′-Hydroxyenones as Mechanistic Probes and Scope-Expanding Surrogates for α,β-Unsaturated Aldehydes in NHC-Catalyzed Reactions
N-heterocyclic carbene catalyzed reactions of α,β-unsaturated aldehydes and a variety of electrophiles allow the facile preparation of a diverse array of annulation products including tri-substituted cyclopentenes, γ-lactams, and bicyclic β-lactams. The substrate scope of these reactions, however, i...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2907655/ https://ncbi.nlm.nih.gov/pubmed/19530737 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja902143w |
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