Synthesis of Chiral Aziridines through Decarboxylative Generation of Sulfur Ylides and their Reaction with Chiral Sulfinyl Imines

Reaction of sulfur ylide with a series of aryl substituted chiral non-racemic sulfinyl imines afforded the corresponding aziridines in high yield and good stereoselection. The sulfur ylides were generated by the thermally induced decarboxylation of carboxymethylsulfonium betaines. A drop in the dias...

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Hlavní autoři: Forbes, David C., Bettigeri, Sampada V., Amin, Sejal R., Bean, Christie J., Law, Amanda M., Stockman, Robert A.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2009
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2906816/
https://ncbi.nlm.nih.gov/pubmed/20664808
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1080/00397910802654898
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