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(2S)-2-[(2S*,5R*,6R*)-5,6-Dimeth­oxy-5,6-dimethyl-1,4-dioxan-2-yl]-1-[(S)-1,1-dimethyl­ethylsulfon­yl]aziridine

The reaction of a sulfur ylide with a chiral non-racemic sulfinyl imine afforded the desired aziridine in excellent yield and subsequent oxidation of the sulfinyl moiety dissolved in anhydrous dichloro­methane using a 75% aqueous solution of 3-chloro­per­oxy­benzoic acid afforded the title compound,...

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Detalhes bibliográficos
Main Authors: Moragas Solà, Toni, Lewis, William, Bettigeri, Sampada V., Stockman, Robert A., Forbes, David C.
Formato: Artigo
Idioma:Inglês
Publicado em: International Union of Crystallography 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3011582/
https://ncbi.nlm.nih.gov/pubmed/21589609
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600536810048816
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