טוען...
Relative Stabilities of Transition States Determine Diastereocontrol in Sulfur Ylide Additions onto Chiral N-Sulfinyl Imines
Additions of methylphenylsulfonium methylide onto chiral non-racemic N-sulfinyl imines (R′-SO-N=CH-R, R′=t-butyl, R=protected diol), followed by ring closure, yield terminal aziridines with high diastereoselectivity. Control reactions have established that both N- and C- iminyl substituents impact p...
שמור ב:
| Main Authors: | , , |
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| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
2012
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| נושאים: | |
| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3278079/ https://ncbi.nlm.nih.gov/pubmed/22345824 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/qua.23020 |
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