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Mechanism and engineering of polyketide chain initiation in fredericamycin biosynthesis

The ability to incorporate atypical primer units through the use of dedicated initiation polyketide synthase (PKS) modules offers opportunities to expand molecular diversity of polyketide natural products. Here we identify the initiation PKS module responsible for hexadienyl priming of the antibioti...

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Detalles Bibliográficos
Main Authors: Das, Abhirup, Szu, Ping-Hui, Fitzgerald, Jay T., Khosla, Chaitan
Formato: Artigo
Idioma:Inglês
Publicado: 2010
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC2904946/
https://ncbi.nlm.nih.gov/pubmed/20540492
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja102517q
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