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A straightforward route to enantiopure α-substituted derivatives of (2S,3aS,7aS)-octahydroindole-2-carboxylic acid

High yielding and remarkably selective alkylations of a suitably protected derivative of (2S,3aS,7aS)-octahydroindole-2-carboxylic acid are described. The fused bicyclic structure of this proline analogue greatly influences the stereochemical outcome of direct alkylation reactions taking place at th...

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Autori principali: Sayago, Francisco J., Calaza, M. Isabel, Jiménez, Ana I., Cativiela, Carlos
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2009
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC2904618/
https://ncbi.nlm.nih.gov/pubmed/20640172
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2009.05.006
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