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Iridium Catalyzed anti-Diastereo- and Enantioselective Carbonyl (Trimethylsilyl)allylation from the Alcohol or Aldehyde Oxidation Level

Using the ortho-cyclometallated π-allyl iridium precatalyst (R)-I derived from [Ir(cod)Cl](2), 4-cyano-3-nitrobenzoic acid, (R)-SEGPHOS and allyl acetate, enantioselective transfer hydrogenation of α-(trimethylsilyl)allyl acetate in the presence of aldehydes 2a–2i mediated by isopropanol delivers pr...

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Bibliografiske detaljer
Main Authors: Han, Soo Bong, Gao, Xin, Krische, Michael J.
Format: Artigo
Sprog:Inglês
Udgivet: 2010
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2904607/
https://ncbi.nlm.nih.gov/pubmed/20540509
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja103299f
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