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Hydroacylation of 2-Butyne from the Alcohol or Aldehyde Oxidation Level via Ruthenium Catalyzed C-C Bond Forming Transfer Hydrogenation
Under the conditions of ruthenium catalyzed transfer hydrogenation, 2-butyne couples to alcohols 1a–1j to deliver α,β-unsaturated ketones 3a–3j in good to excellent isolated yields with complete E-stereoselectivity. Under identical conditions, aldehydes 2a–2j couple to 2-butyne to provide an identic...
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| Egile Nagusiak: | , , , |
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| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
2009
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| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2897757/ https://ncbi.nlm.nih.gov/pubmed/20613891 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2009.03.068 |
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