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A Formal Synthesis of the C1-C9 Fragment of Amphidinolide C Employing the Tamaru Reaction
[Image: see text] Homoallylation of aldehydes with isoprene and triethyl borane, catalyzed by Ni(acac)(2) gave hydroxy alkenes in good yield with excellent regio- and stereoselectivity. Cross metathesis of the hydroxy alkenes with methyl acrylate using second generation Grubbs catalyst and copper(I)...
Bewaard in:
| Hoofdauteurs: | , , |
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| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
2010
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2896498/ https://ncbi.nlm.nih.gov/pubmed/20527780 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol100959a |
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