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Total Synthesis of Amphidinolide E and Amphidinolide E Stereoisomers

Four amphidinolide E stereoisomers, amphidinolide E (1), 2-epi-amphidinolide E (2), 19-epi-amphidinolide E (3), and 2-epi-19-epi-amphidinolide E (4), have been synthesized via the judicious union of aldehyde 5, allylsilanes 7 or 8, acids 9 or 10, and vinylstannane 6. The C19 stereocenters of the C19...

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Bibliografiske detaljer
Main Authors: Va, Porino, Roush, William R.
Format: Artigo
Sprog:Inglês
Udgivet: 2007
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2031846/
https://ncbi.nlm.nih.gov/pubmed/18575572
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2007.02.058
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