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Synthesis of the C3–C18 Fragment of Amphidinolides G and H
A synthesis of an amphidinolides G and H C3–C18 subunits is reported. The C10–C18 segment 4 was prepared by a Negishi cross-coupling, whereas the synthesis of the C3–C9 fragment 5 employed an asymmetric cyanosilylation as the key step. The two segments were coupled by lithiation of iodide 4 and trap...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2583364/ https://ncbi.nlm.nih.gov/pubmed/17616200 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol071024e |
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