Enantioselective Iridium Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level via Transfer Hydrogenative Coupling of Allyl Acetate: Departure from Chirally Modified Allyl Metal Reagents in Carbonyl Addition

Under the conditions of transfer hydrogenation employing an iridium catalyst generated in situ from [Ir(cod)Cl](2), the chiral phosphine ligands (R)-BINAP or (R)-Cl,MeO-BIPHEP and m-nitrobenzoic acid, allyl acetate couples to allylic alcohols 1a-1c, aliphatic alcohols 1d-1l and benzylic alcohols 1m-...

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Hlavní autoři: Kim, In Su, Ngai, Ming-Yu, Krische, Michael J.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2008
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Article
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2890235/
https://ncbi.nlm.nih.gov/pubmed/18841896
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja805722e
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