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Characterization of the Terminal Iron(IV) Imides {[PhBP(tBu)(2)(pz’)]Fe(IV)≡NAd}(+)
New hybrid bis(phosphine)(pyrazole)borate tripodal ligands ([PhBP(tBu)(2)(pz’)](−)) are reported that support pseudotetrahedral iron in the oxidation states +1, +2, +3, and +4. The higher oxidation states are stabilized by a terminal Fe≡NR linkage. Of particular interest is the generation and thorou...
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| Autors principals: | , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2006
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2888259/ https://ncbi.nlm.nih.gov/pubmed/16608321 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja0604358 |
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