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Total Synthesis of (+)-Sieboldine A
The first total synthesis of (+)-sieboldine A was completed in 20 steps from readily available (3aS,6aR)-3,3a,4,6-atetrahydro-2H-cyclopenta[b]furan-2-one (5). Key steps are: (a) a pinacol-terminated 1,6-enyne cyclization reaction to form the cis-hydrindanone core (11 → 12), (b) formation of the spir...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2885033/ https://ncbi.nlm.nih.gov/pubmed/20527933 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja103666n |
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