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Reduction of Nitrous Oxide to Dinitrogen by a Mixed Valent Tricopper-Disulfido Cluster
The greenhouse gas N(2)O is converted to N(2) by a µ-sulfido-tetracopper active site in the enzyme nitrous oxide reductase (N(2)OR) via a process postulated to involve µ-1,3 coordination of N(2)O to two Cu(I) ions. In efforts to develop synthetic models of the site with which to test mechanistic hyp...
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| 主要な著者: | , , , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2009
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2880652/ https://ncbi.nlm.nih.gov/pubmed/19206272 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja808917k |
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