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Ligand Structural Effects on Cu(2)S(2) Bonding and Reactivity in Side-On Disulfido-Bridged Dicopper Complexes
In order to assess supporting ligand effects on S-S bond activation, a series of [Cu(2)(μ-η(2):η(2)-S(2))](2+) complexes supported by various β-diketiminate or anilido-imine ligands (L) were synthesized via the reaction of Cu(I) precursors LCu(CH(3)CN) with S(8). For the cases where L = β-diketimina...
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| Main Authors: | , , , , |
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| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2007
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2519136/ https://ncbi.nlm.nih.gov/pubmed/17279827 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic061589r |
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