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Ligand Structural Effects on Cu(2)S(2) Bonding and Reactivity in Side-On Disulfido-Bridged Dicopper Complexes

In order to assess supporting ligand effects on S-S bond activation, a series of [Cu(2)(μ-η(2):η(2)-S(2))](2+) complexes supported by various β-diketiminate or anilido-imine ligands (L) were synthesized via the reaction of Cu(I) precursors LCu(CH(3)CN) with S(8). For the cases where L = β-diketimina...

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Detalhes bibliográficos
Main Authors: Brown, Eric C., Bar-Nahum, Itsik, York, John T., Aboelella, Nermeen W., Tolman, William B.
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2519136/
https://ncbi.nlm.nih.gov/pubmed/17279827
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic061589r
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