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Mechanistic Aspects of the Formation of Guanidinohydantoin from Spiroiminodihydantoin under Acidic Conditions

Experimentally, it was observed that the oxidized guanine lesion spiroiminodihydantoin (Sp) contained in highly purified oligodeoxynucleotides slowly converts to guanidinohydantoin (Gh). The reaction is accelerated in the presence of acid. The possible mechanisms of this transformation have been ana...

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Detalhes bibliográficos
Main Authors: Ye, Yu, Munk, Barbara H., Muller, James G., Cogbill, Alexander, Burrows, Cynthia J., Schlegel, H. Bernhard
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2880634/
https://ncbi.nlm.nih.gov/pubmed/19146379
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/tx800402y
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