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Mechanism of Lithium Diisopropylamide-Mediated Substitution of 2,6-Difluoropyridine
Treatment of 2,6-difluoropyridine with lithium diisopropylamide in THF solution at −78 °C effects ortholithiation quantitatively. Warming the solution to 0 °C converts the aryllithium to 2-fluoro-6-(diisopropylamino)pyridine. Rate studies reveal evidence of a reversal of the ortholithiation and a su...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2872121/ https://ncbi.nlm.nih.gov/pubmed/20397635 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja910834b |
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