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Diastereo- and Enantioselective Hydrogenative Aldol Coupling of Vinyl Ketones: Design of an Effective Monodentate TADDOL-Based Phosphonite Ligand
[Image: see text] We report the first enantioselective reductive aldol couplings of vinyl ketones, which required the design of a novel monodentate TADDOL-based phosphonite ligand. Specifically, hydrogenation of commercially available methyl vinyl ketone (MVK) or ethyl vinyl ketone (EVK) in the pres...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2008
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2860773/ https://ncbi.nlm.nih.gov/pubmed/18266373 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja710862u |
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