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Phosphine-Catalyzed Formation of Carbon–Sulfur Bonds: Catalytic Asymmetric Synthesis of γ-Thioesters
[Image: see text] A method for the catalytic asymmetric γ sulfenylation of carbonyl compounds has been developed. In the presence of an appropriate catalyst, thiols not only add to the γ position of allenoates, overcoming their propensity to add to the β position in the absence of a catalyst, but do...
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| Autors principals: | , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2010
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2850260/ https://ncbi.nlm.nih.gov/pubmed/20222657 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja101251d |
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