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Phosphine-catalyzed asymmetric additions of malonate esters to γ-substituted allenoates and allenamides

Because carbonyl groups are ubiquitous in organic chemistry, the ability to synthesize functionalized carbonyl compounds, particularly enantioselectively, is an important objective. We have developed a straightforward and versatile method for catalytic asymmetric carbon–carbon bond formation at the...

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Detalhes bibliográficos
Main Authors: Sinisi, Riccardo, Sun, Jianwei, Fu, Gregory C.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2996437/
https://ncbi.nlm.nih.gov/pubmed/20624987
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1003597107
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