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Phosphine-Catalyzed Formation of Carbon–Sulfur Bonds: Catalytic Asymmetric Synthesis of γ-Thioesters

[Image: see text] A method for the catalytic asymmetric γ sulfenylation of carbonyl compounds has been developed. In the presence of an appropriate catalyst, thiols not only add to the γ position of allenoates, overcoming their propensity to add to the β position in the absence of a catalyst, but do...

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Hlavní autoři: Sun, Jianwei, Fu, Gregory C.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2010
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2850260/
https://ncbi.nlm.nih.gov/pubmed/20222657
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja101251d
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