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Enantioselective [3 + 2] annulation of α-substituted allenoates with β,γ-unsaturated N-sulfonylimines catalyzed by a bifunctional dipeptide phosphine

The first enantioselective [3 + 2] annulation of α-substituted allenoates with β,γ-unsaturated N-sulfonylimines is described. In the presence of a dipeptide phosphine catalyst, a wide range of highly functionalized cyclopentenes bearing an all-carbon quaternary center were obtained in moderate to go...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Ni, Huanzhen, Yao, Weijun, Lu, Yixin
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4778533/
https://ncbi.nlm.nih.gov/pubmed/26977194
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.12.37
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