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Total Synthesis of Cyclosporine: Access to N-Methylated Peptides via Isonitrile Coupling Reactions

[Image: see text] Recent developments in the use of isonitriles to furnish secondary and tertiary amide bond formations are applied to a novel total synthesis of the important cyclic polypeptide cyclosporine A. Specifically, the disclosed synthetic route demonstrates the utility of microwave-mediate...

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Autori principali: Wu, Xiangyang, Stockdill, Jennifer L., Wang, Ping, Danishefsky, Samuel J.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2010
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC2844917/
https://ncbi.nlm.nih.gov/pubmed/20199071
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja100517v
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