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Intrinsic reactivity and driving force dependence in concerted proton–electron transfers to water illustrated by phenol oxidation

Three experimental techniques, laser flash photolysis, redox catalysis, and stopped-flow, were used to investigate the variation of the oxidation rate constant of phenol in neat water with the driving force offered by a series of electron acceptors. Taking into account a result previously obtained w...

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Hlavní autoři: Bonin, Julien, Costentin, Cyrille, Louault, Cyril, Robert, Marc, Routier, Mathilde, Savéant, Jean-Michel
Médium: Artigo
Jazyk:Inglês
Vydáno: National Academy of Sciences 2010
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2840485/
https://ncbi.nlm.nih.gov/pubmed/20139306
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0914693107
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