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Intrinsic reactivity and driving force dependence in concerted proton–electron transfers to water illustrated by phenol oxidation
Three experimental techniques, laser flash photolysis, redox catalysis, and stopped-flow, were used to investigate the variation of the oxidation rate constant of phenol in neat water with the driving force offered by a series of electron acceptors. Taking into account a result previously obtained w...
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| Main Authors: | , , , , , |
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| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
National Academy of Sciences
2010
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2840485/ https://ncbi.nlm.nih.gov/pubmed/20139306 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0914693107 |
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