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Origins of Regioselectivity and Alkene-Directing Effects in Nickel-Catalyzed Reductive Couplings of Alkynes and Aldehydes
Origins of regioselectivity and alkene-directing effects in nickel-catalyzed reductive coupling reactions were investigated by density functional calculations. Regioselectivity of simple alkynes is controlled by steric effects, while conjugated enynes and diynes are predicted to have increased react...
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| Главные авторы: | , , , , |
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| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2010
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2830786/ https://ncbi.nlm.nih.gov/pubmed/20095609 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja909562y |
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