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Origins of Regioselectivity and Alkene-Directing Effects in Nickel-Catalyzed Reductive Couplings of Alkynes and Aldehydes
Origins of regioselectivity and alkene-directing effects in nickel-catalyzed reductive coupling reactions were investigated by density functional calculations. Regioselectivity of simple alkynes is controlled by steric effects, while conjugated enynes and diynes are predicted to have increased react...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2830786/ https://ncbi.nlm.nih.gov/pubmed/20095609 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja909562y |
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