A Source for the Special Catalytic Power of Enzymes: Orbital Steering
The velocities of acid catalyzed esterification and γ-lactonizations were studied to test the sensitivity of a chemical reaction to the orientation of the reacting atoms. Variation in orientation of the attacking oxygen atom relative to the carbon atom of the carboxylic acid was achieved by using bi...
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| Veröffentlicht in: | Proc Natl Acad Sci U S A |
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| Hauptverfasser: | , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
National Academy of Sciences
1970
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| Schlagworte: | |
| Online-Zugang: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC283065/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16591843/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.66.2.445 |
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