Oxygenation of Cobalt Porphyrinates: Coordination or Oxidation?

The X-ray characterization of the five-coordinate picket-fence porphyrin complex, [Co(TpivPP)(2-MeHim)], is reported. The complex has the displacement of cobalt from the porphyrin plane = 0.15 Å, and Co–N(Im) = 2.145 (3) and (Co–N(p))(av) = 1.979(3) Å. This five-coordinate complex, in the presence o...

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Autores principales: Li, Jianfeng, Noll, Bruce C., Oliver, Allen G., Ferraudi, Guillermo, Lappin, A. Graham, Scheidt, W. Robert
Formato: Artigo
Lenguaje:Inglês
Publicado: 2010
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Article
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC2826529/
https://ncbi.nlm.nih.gov/pubmed/20104874
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic902309f
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