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Structural Insights into Ligand Dynamics: Correlated Oxygen and Picket Motion in Oxycobalt Picket Fence Porphyrins
Two different oxygen-ligated cobalt porphyrins have been synthesized and the solid-state structures have been determined at several temperatures. The solid-state structures provide insight into the dynamics of Co–O(2) rotation and correlation with protecting group disorder. [Co(TpivPP)(1-EtIm)(O(2))...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3384769/ https://ncbi.nlm.nih.gov/pubmed/22642824 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja303475a |
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