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Structural Insights into Ligand Dynamics: Correlated Oxygen and Picket Motion in Oxycobalt Picket Fence Porphyrins

Two different oxygen-ligated cobalt porphyrins have been synthesized and the solid-state structures have been determined at several temperatures. The solid-state structures provide insight into the dynamics of Co–O(2) rotation and correlation with protecting group disorder. [Co(TpivPP)(1-EtIm)(O(2))...

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Bibliografiske detaljer
Main Authors: Li, Jianfeng, Noll, Bruce C., Oliver, Allen G., Scheidt, W. Robert
Format: Artigo
Sprog:Inglês
Udgivet: 2012
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3384769/
https://ncbi.nlm.nih.gov/pubmed/22642824
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja303475a
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