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Relative Axial Ligand Orientation in Bis(imidazole)iron(II) Porphyrinates: Are “Picket Fence” Derivatives Different?
The synthesis of three new bis(imidazole)-ligated iron(II) picket fence porphyrin derivatives, [Fe(TpivPP)(1-RIm)(2)] 1-RIm = 1-methyl-, 1-ethyl-, or 1-vinylimidazole) are reported. X-ray structure determinations reveal that the steric requirements of the four α,α,α,α-o-pivalamidophenyl groups lead...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2008
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2543116/ https://ncbi.nlm.nih.gov/pubmed/18351735 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic702498c |
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