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Oxygenation of Cobalt Porphyrinates: Coordination or Oxidation?
The X-ray characterization of the five-coordinate picket-fence porphyrin complex, [Co(TpivPP)(2-MeHim)], is reported. The complex has the displacement of cobalt from the porphyrin plane = 0.15 Å, and Co–N(Im) = 2.145 (3) and (Co–N(p))(av) = 1.979(3) Å. This five-coordinate complex, in the presence o...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2826529/ https://ncbi.nlm.nih.gov/pubmed/20104874 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic902309f |
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