Oxygenation of Cobalt Porphyrinates: Coordination or Oxidation?

The X-ray characterization of the five-coordinate picket-fence porphyrin complex, [Co(TpivPP)(2-MeHim)], is reported. The complex has the displacement of cobalt from the porphyrin plane = 0.15 Å, and Co–N(Im) = 2.145 (3) and (Co–N(p))(av) = 1.979(3) Å. This five-coordinate complex, in the presence o...

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Bibliographic Details
Main Authors:	Li, Jianfeng, Noll, Bruce C., Oliver, Allen G., Ferraudi, Guillermo, Lappin, A. Graham, Scheidt, W. Robert
Format:	Artigo
Language:	Inglês
Published:	2010
Subjects:	Article
Online Access:	https://ncbi.nlm.nih.gov/pmc/articles/PMC2826529/ https://ncbi.nlm.nih.gov/pubmed/20104874 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic902309f
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Oxygenation of Cobalt Porphyrinates: Coordination or Oxidation?

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