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Near-Stoichiometric Conversion of H(2)O(2) to Fe(IV)=O at a Non-Heme Iron(II) Center. Insights Into the O-O Bond Cleavage Step
[Image: see text] Near-quantitative formation of an oxoiron(IV) intermediate [Fe(IV)(O)(TMC)(CH(3)CN)](2+) (2) from stoichiometric H(2)O(2) was achieved with [Fe(II)(TMC)](2+) (1) (TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraaza-cyclotetradecane). This important outcome is best rationalized by invoking...
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| Hauptverfasser: | , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2010
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2823852/ https://ncbi.nlm.nih.gov/pubmed/20121136 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja9101908 |
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