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Synthesis of Medium-Bridged Twisted Lactams via Cation–π Control of Regiochemistry of Intramolecular Schmidt Reaction

[Image: see text] Medium-bridged twisted amides can be synthesized by the intramolecular Schmidt reaction of 2-azidoalkyl ketones. In these reactions, the regiochemistry of the Schmidt reaction is diverted into a typically disfavored pathway by the presence of an aromatic group at the α-position adj...

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Gorde:
Xehetasun bibliografikoak
Egile Nagusiak: Szostak, Michal, Yao, Lei, Aubé, Jeffrey
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2010
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC2821462/
https://ncbi.nlm.nih.gov/pubmed/20095596
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo902574m
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