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Cation–π Control of Regiochemistry of Intramolecular Schmidt Reactions en Route to Bridged Bicyclic Lactams

The regiochemistry of the intramolecular Schmidt reaction of 2-substituted ketones has proved susceptible to control by the placement of an aromatic group at an adjacent position, permitting the selective formation of a series of bridged bicyclic lactams from these substrates. This phenomenon is asc...

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Detalhes bibliográficos
Main Authors: Yao, Lei, Aubé, Jeffrey
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2596723/
https://ncbi.nlm.nih.gov/pubmed/17302421
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja068919r
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