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Perylenequinone Natural Products: Total Synthesis of Hypocrellin A

[Image: see text] An efficient and stereoselective total synthesis of the perylenequinone natural product hypocrellin A (1) is described. The key features include a potentially biomimetic 1,8-diketone aldol cyclization to set the centrochiral C7,C7’-stereochemistry, bis(trifluoroacetoxy)iodobenzene...

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Main Authors: O’Brien, Erin M., Morgan, Barbara J., Mulrooney, Carol A., Carroll, Patrick J., Kozlowski, Marisa C.
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2010
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC2798931/
https://ncbi.nlm.nih.gov/pubmed/19894741
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo901386d
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