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Perylenequinone Natural Products: Total Synthesis of Hypocrellin A
[Image: see text] An efficient and stereoselective total synthesis of the perylenequinone natural product hypocrellin A (1) is described. The key features include a potentially biomimetic 1,8-diketone aldol cyclization to set the centrochiral C7,C7’-stereochemistry, bis(trifluoroacetoxy)iodobenzene...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2798931/ https://ncbi.nlm.nih.gov/pubmed/19894741 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo901386d |
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