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Syntheses of aminoalcohol-derived macrocycles leading to a small-molecule binder to and inhibitor of Sonic Hedgehog

We report the synthesis and biological activity of a library of aminoalcohol-derived macrocycles from which robotnikinin (17), a binder to and inhibitor of Sonic Hedgehog, was derived. Using an asymmetric alkylation to set a key stereocenter and an RCM reaction to close the macrocycle, we were able...

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Hlavní autoři: Peng, Lee F., Stanton, Benjamin Z., Maloof, Nicole, Wang, Xiang, Schreiber, Stuart L.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2009
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2796117/
https://ncbi.nlm.nih.gov/pubmed/19819139
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.bmcl.2009.09.089
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